Well, i kinda watched the Spiderman and his amazing friends, Iceman and Firestar.
 
So i wanna know if they kinda have a relationship in either the cartoon series or in comics.
 
 

I don't believe it was every confirmed or not. I think they were just supposed to be friends along with Spidey. I believe the only man she's ever had a relationship with was Justice and that was during their run as New Warriors then as Avengers.

yeah.

Only in the cartoon.  They had a flashback to when Peter Parker first met his Amazing Friends, and Bobby was jealous of how close Peter was with Angelica.  However, she had dated Flash Thompson & was romantically linked with Sunfire.  Yet her personality was a lot more outgoing... a lot more like Mary Jane (whom she closely resembled when in civilian clothing).

They dated for some time

" They dated for some time "

Iceman has had many jokes about him being gay (especially in a Family Guy sketch) but he's dated some of Marvel's prettiest ladies.  But most of them were probably Mystique in disguise :p

I thought Marvel has been toying with the idea of him turning gay? "

For some reason I always thought they were dating on "Amazing Friends" although I'm not sure if I ever saw anything to support that. Maybe it's just the Fire/Ice thing. I'm sure he wanted to date her, though.

i thought her and spidey hooked up in spiderman and his amazing friends cartoon or maybe they just kissed once i was a child then so my memory might not be great.