I'll be breaking down under the idea Lucario is locked to 4 moves which would probably be some of his more iconic ones being Aura Sphere, Force Palm, Bone Rush, and extreme speed with no room for his elemental,steel type moves or stat buffing moves but I don't think they'd make too much of a difference since I do think any solid hit from Lucario could possibly be enough to one shot or severely debilitate Aang too the point he'd have small chance to continue afterwards.
I don't trust pokedex entries since they've always been pretty inconsistent outside of some Legendries IMO. Most pokemon have no feats to imply their entries should be 100 percent believed especially since so many have contradictions. But going by just anime feats of a "Peak" lucario with moves like Aura Sphere and its aura sensing. I'd say Aang wouldn't be able to take many hits and Lucario can close the distance for a win imo and being bloodlusted means Aang won't be using his more evasive style which would of helped him a decent bit. Lucario 8.5/10
AS Vs ME is harder since it becomes even more Zoning vs CQC. Not sure if Lucario can get it for a one shot mostly due to air bending and the free flight he has in AS. Aang would have to go pretty hard in putting him down and with his air bending and firebending in the AS state he could probably do it before Lucario could land the hit. Aang 7/10
Course if you believe in higher tier scaling for Pokemon and pokedex feats Lucario stomps both rounds but thats just boring to think about.
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